As intimidating as it may seem, every reading has its place. 中 is a wonderful example of a kanji that has a myriad of readings depending on the word it appears in.
中(なか) itself means inside.
授業中に(じゅぎょうちゅうに) means during class.
一日中に(いちにちじゅうに) means all day long.
私は一日中に授業中にかばんの中にあったねこを見まし た。
わたしはいちにちじゅうにじゅぎゅうちゅうにかばんの なかにあったねこをみました。
All day long during class, I watched the cat that was in the bag.
Sure, that sentence is silly, but I'm pretty sure it's grammatically correct and shows some of the uses of 中.
Two others that have large entries in kanji dictionaries are 下(below/under) and 上(above/on).
Just keep at it and you'll do fine. Kanji are pretty fun, and as long as you learn more and more vocabulary (and how they're written in kanji), it's not too hard to pick up the readings.