~たところで has many meanings/functions. For instance, 今家を出たところで can be interpreted also as "ところ as the moment + で for the continuous usage of the -te form of copula", i.e., ちょうど今家を出たところだから because I've just left home. If you want to use ところで as "as if" in those sentences, you need to make the meaning clearer, using たとえ or もし. Also, ~たところで as "even if" is a conditional clause, so the subject marker must be が. When は is used, the subject of the main clause must be the same as the one of the subordinate clause.
I would say;
たとえ僕が今すぐ家を出たところで、彼女を助けられない。
たとえ今すぐ家を出たところで、僕は彼女を助けられない。
君がこれを買ったところで、価値は上がらない。
(君は can't be used here since the subject of the main clause is not 君.)
あいつは、たとえ質問が分かったところで、答えなかっただろう。
~ても or ~としても is more common and natural for all these cases.