There are 24 permutations of those four kanji.
明日香村
明日村香
明香日村
明香村日
明村日香
明村香日
日明香村
日明村香
日香明村
日香村明
日村明香
日村香明
香明日村
香明村日
香日明村
香日村明
香村明日
香村日明
村明日香
村明香日
村日明香
村日香明
村香明日
村香日明
Among these ones, only a few permutations can make sense.
1. 日村 香明 Himura Takaaki (or Yoshiaki)
2. 日村 明香 Himura Akika
3. 香村 日明 Kōmura Haruaki
4. 香日村 明 Kasugamura Akira
5. 明村 日香 Akimura Haruka
6. 明日村 香 Asumura Kaori
These are all people's names (surname - given name), but not so common ones. (#1, 3, 4 are male names, and the rest are female names.) Other than people's names, 明日村香 could be a fictional name of a fragrance "Asumura-kō", but not common, either. Anyway, these are all "proper noun" rather than "word".
To tell the truth, since 明日香村 is a relatively well-known village, Japanese people or people who are fluent in Japanese enough to be able to find out these possible names would be able to get the correct answer 明日香村 relatively easily. Probably to get the correct answer would be easier than to think of these wrong answers, in my impression.