Yes the te-form or masu form is called 連用形 in Japanese and is the 2nd form of verb conjunction. As the word implies, it is used to join.
Both 破り and 破い is valid.
ついに is an adverb. Adverbs precedes the verb it modifies unlike English which is the opposite. In this case it modifies 復活. Resurrected at long last.
Just like 速く走る run quickly. 丁寧に梱包する packs neatly/carefully/with care.
In your last sentence, ついに is modifying 得る. To obtain at long last.
Also ついに登場、発表 etc, these aren't nouns, well they are but in this case they are サ変 verbs with the 送り仮名 chopped off. This is common in headlines as it gives more impact as evident by Japanese newspapers. The full sentence should be ついに登場する!but the kana just get in the way so the drop it.
Newspaper do this all the time. Eg
新藤総務相が靖国神社参拝 中韓の反発強まる可能性
If you put all the kana in it would be
新藤総務相が靖国神社を参拝することに 中韓の反発が強まる可能性がある
Less impact, doesn't add anything, waste more ink and space so they just drop obvious particles.