"-Masu" is attached to verbs, whereas "-desu" is for na-adjectives / nouns. The explanatory "no / n" belongs to nouns, therefeore "-desu" is used for it. "- Desu" is also used for i-adjectives or the negative form / -tai form of verbs, which is treated as an i-adjective. However, this "-desu" is not a copula but a polite suffix that does not have inflections.