Usui!
I watched Kaichou wa Maid Sama recently and fell in love with it. I now have a collection of all the manga in my room, because it was just amazing.
I am not a big fan of romantic animes, and I hate it when people like Misaki don't understand the romantic advances from her counterpart (Usui), but how could I not love this.
Usui went straight to the top on my list of fav anime males, overtaking the spot that was being tied by Lelouch vi Britannia and Light Yagami.